Gold(III) Triggered Transformations of 22-Methyl-m-benziporphyrin Involving an Effective Contraction of Benzene to Cyclopentadiene
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- 作者：Karolina Hurej ; Dr. Miłosz Pawlicki and Prof. Lechosław Latos-Grażyński
- 刊名：Chemistry - A European Journal
- 出版年：2017
- 出版时间：February 10, 2017
- 年：2017
- 卷：23
- 期：9
- 页码：2059-2066
- 全文大小：1620K
- ISSN：1521-3765
文摘
A structurally prearranged carbaporphyrin, 22-methyl-m-benziporphyrin, provided the perfect macrocyclic platform to form gold(III) 22-methyl-m-benziporphyrin, which facilitates the specific m-benzene ring contraction yielding gold(III) 21-methyl 21-carbaporphyrin with remarkably high yield.