ChemInform Abstract: Palladium-Catalyzed C—S Bond Formation of Stable Enamines with Arene/Alkanethiols: Highly Regioselective Synthesis of β-Amino Sulfides.

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• 作者：Yaojia Jiang ; Gaohui Liang ; Cong Zhang and Teck-Peng Loh
• 刊名：ChemInform
• 出版年：2016
• 出版时间：November, 2016
• 年：2016
• 卷：47
• 期：48
• 全文大小：33K
• ISSN：1522-2667

文摘

A direct and regiocontrolled thiolation of stable enamines provides E-configurated β-amino sulfides through a palladium-catalyzed C(sp²)—H functionalization under mild conditions using a phosphine ligand to prevent poisoning of the catalyst by S.