Tunable Oxygen Functional Groups as Electrocatalysts on Graphite Felt Surfaces for All-Vanadium Flow Batteries
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- 作者：Dr. Luis Estevez ; Dr. David Reed ; Zimin Nie ; Ashleigh M Schwarz ; Dr. Manjula I. Nandasiri ; Dr. James P Kizewski ; Dr. Wei Wang ; Edwin Thomsen ; Dr. Jun Liu ; Dr. Ji-Guang Zhang ; Dr. Vincent Sprenkle and Dr. Bin Li
- 刊名：ChemSusChem
- 出版年：2016
- 出版时间：June 22, 2016
- 年：2016
- 卷：9
- 期：12
- 页码：1455-1461
- 全文大小：1080K
- ISSN：1864-564X
文摘
A dual oxidative approach using O2 plasma followed by treatment with H2O2 to impart oxygen functional groups onto the surface of a graphite felt electrode. When used as electrodes for an all-vanadium redox flow battery (VRB) system, the energy efficiency of the cell is enhanced by 8.2 % at a current density of 150 mA cm−2 compared with one oxidized by thermal treatment in air. More importantly, by varying the oxidative techniques, the amount and type of oxygen groups was tailored and their effects were elucidated. It was found that O−C=O groups improve the cells performance whereas the C−O and C=O groups degrade it. The reason for the increased performance was found to be a reduction in the cell overpotential after functionalization of the graphite felt electrode. This work reveals a route for functionalizing carbon electrodes to improve the performance of VRB cells. This approach can lower the cost of VRB cells and pave the way for more commercially viable stationary energy storage systems that can be used for intermittent renewable energy storage.