Heteroatom (N or N-S)-Doping Induced Layered and Honeycomb Microstructures of Porous Carbons for COb>2b> Capture and Energy Applications

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• 作者：Wenjie Tian ; Huayang Zhang ; Hongqi Sun ; Alexandra Suvorova ; Martin Saunders ; Moses Tade and Shaobin Wang
• 刊名：Advanced Functional Materials
• 出版年：2016
• 出版时间：December 20, 2016
• 年：2016
• 卷：26
• 期：47
• 页码：8651-8661
• 全文大小：3566K
• ISSN：1616-3028

文摘

Increasing global challenges such as climate change, environmental pollution, and energy shortage have stimulated the worldwide explorations into novel and clean materials for their applications in the capture of carbon dioxide, a major greenhouse gas, and toxic pollutants, energy conversion, and storage. In this study, two microstructured carbons, namely N-doped pillaring layered carbon (NC) and N, S codoped honeycomb carbon (NSC), have been fabricated through a one-pot pyrolysis process of a mixture containing glucose, sodium bicarbonate, and urea or thiourea. The heteroatom doping is found to induce tailored microstructures featuring highly interconnected pore frameworks, high spp>2p>-C ratios, and high surface areas. The formation mechanism of the varying pore frameworks is believed to be hydrogen-bond interactions. NSC displays a similar COb>2b> adsorption capacity (4.7 mmol gp>−1p> at 0 °C), a better COb>2b>/Nb>2b> selectivity, and higher activity in oxygen reduction reaction as compared with NC-3 (the NC sample with the highest N content of 7.3%). NSC favors an efficient four-electron reduction pathway and presents better methanol tolerance than Pt/C in alkaline media. The porous carbons also exhibit excellent rate performance as supercapacitors.