The Diphosphorus Complex [Cp₂Mo₂(CO)₄(η²-P₂)] as a Building Block for the Synthesis of Mixed-Hybrid Coordination Polymers

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• 作者：Mehdi Elsayed Moussa ; Bianca Attenberger ; Martin Fleischmann ; Andrea Schreiner and Manfred Scheer
• 刊名：European Journal of Inorganic Chemistry
• 出版年：2016
• 出版时间：October 2016
• 年：2016
• 卷：2016
• 期：28
• 页码：4538-4541
• 全文大小：788K
• ISSN：1099-0682c

文摘

The three-component reaction of the tetrahedral diphosphorus complex [Cp₂Mo₂(CO)₄(η²-P₂)] (1), with Ag[BF₄] (2) in the presence of 2,2′-bipyrimidine (3) leads to the formation of the two novel two-dimensional networks 4 and 5. Compound 4 is a new two-dimensional organometallic-organic hybrid polymer, while derivative 5 represents a unique two-dimensional organometallic-inorganic-organic hybrid polymer. These results show the possibility of synthesizing a new class of coordination polymers, which could not be obtained from two-component reactions with organic molecules in addition of metal ions.