刊名:Zeitschrift f蹲 anorganische und allgemeine Chemie
出版年:2016
出版时间:July 2016
年:2016
卷:642
期:14
页码:793-795
全文大小:196K
ISSN:1521-3749
文摘
The synthesis and structural characterization of trans-[IrCl(NO)(PtBu2H)2]BF4 (1) is reported. The title compound was prepared in good yield in the reaction of in situ-prepared trans-[IrCl(coe)(PtBu2H)2] (coe = cis-cyclooctene) with an appropriate amount of nitrosonium tetrafluoridoborate in dichloromethane at room temperature. Single crystals of 1 were grown from dichloromethane/diethyl ether and were analyzed by X-ray crystallography.