ChemInform Abstract: Deoxygenative C—C Bond-Forming Processes via a Net Four-Electron Reductive Coupling.

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• 作者：David P. Todd ; Benjamin B. Thompson ; Alex J. Nett and John Montgomery
• 关键词：C-C bond formation ; alkenes (acyclic compounds) ; alkenes (benzene compounds)
• 刊名：ChemInform
• 出版年：2016
• 出版时间：March, 2016
• 年：2016
• 卷：47
• 期：12
• 全文大小：28K
• ISSN：1522-2667

文摘

Deoxygenative coupling of enones or enals with alkynes is rendered possible with a reagent combination of Et₃SiH and Ti(OiPr)₄ and a nickel carbene complex as catalyst furnishing skipped dienes in moderate to good yields.