Kinetics and thermodynamics of oxidation mediated reaction in l-cysteine and its methyl and ethyl esters in dimethyl sulfoxide-d₆ by NMR spectroscopy

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• 作者：Ryan J. Dougherty^a ; ¹ ; Jaideep Singh^a ; V.V. Krishnan^a ; ^b ; ^{krish@csufresno.edu} ; ^{vvkrishnan@ucdavis.edu}
• 关键词：NMR ; 1H ; 13C ; Oxidation ; Kinetics ; Solvent effect ; l-cysteine. l-Cysteine methyl ester (L-CysME) and l-Cysteine ethyl ester (L-CysEE) ; Short title
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 March 2017
• 年：2017
• 卷：1131
• 期：Complete
• 页码：196-200
• 全文大小：734 K
• 卷排序：1131

文摘

Oxidation induced changes of l-Cysteine and its methyl and ethyl esters in DMSO-d6 Real time NMR measurements Kinetic and thermodynamic parameters via pseudo-first-order rate process.