Coordination environment around the lithium cation in solid Li₂(EMIm)(N(SO₂CF₃)₂)₃ (EMIm = 1-ethyl-3-methylimidazolium): Structural clue of ionic

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• 作者：Kazuhiko Matsumoto ; Rika Hagiwara and Osamu Tamada
• 关键词：Ionic liquid ; Lithium battery ; Room temperature molten salt ; Room temperature ionic liquid ; Bis(trifluoromethylsulfonyl)amide ; Structure
• 刊名：Solid State Sciences
• 出版年：2006
• 出版时间：September 2006
• 年：2006
• 卷：8
• 期：9
• 页码：1103-1107
• 全文大小：227 K

文摘

Crystal structure of Li₂(EMIm)(N(SO₂CF₃)₂)₃ (EMIm = 1-ethyl-3-methylimidazolium cation) has been determined by single-crystal X-ray diffraction as a structural clue of ionic liquid electrolytes for lithium batteries. Li₂(EMIm)(N(SO₂CF₃)₂)₃ crystallizes in the space group e=""mml8"">e=""text-decoration:none; color:black"" href=""/science?_ob=MathURL&_method=retrieve&_udi=B6W6W-4K4WH95-1&_mathId=mml8&_user=10&_cdi=6609&_rdoc=17&_handle=V-WA-A-W-WU-MsSAYZW-UUW-U-AAZCAWYZAC-AAZWDUEVAC-BEWUAVZE-WU-U&_acct=C000050221&_version=1&_userid=10&md5=ba040e31578263160c4676659d40c214"" title=""Click to view the MathML source"">P2₁/c, e=""mml9"">e=""text-decoration:none; color:black"" href=""/science?_ob=MathURL&_method=retrieve&_udi=B6W6W-4K4WH95-1&_mathId=mml9&_user=10&_cdi=6609&_rdoc=17&_handle=V-WA-A-W-WU-MsSAYZW-UUW-U-AAZCAWYZAC-AAZWDUEVAC-BEWUAVZE-WU-U&_acct=C000050221&_version=1&_userid=10&md5=092be8e46abf385cfc41bd3f95842379"" title=""Click to view the MathML source"">a