Studies on the Ru(II) monocationic complexes [RuCl2(NO)(P-N)(PR3)]PF6, where P-N = o-diphenylphosphino-N,N-dimethylaniline, and R = Ph and p-X-C6H4 (X = OMe, Me, F)
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- 作者：Juliana P. da Silvaa ; Francisco D. Fagundesa ; Davi F. Backb ; Javier Ellenac ; Brian R. Jamesd ; Má ; rcio P. de Araujoa ; mparaujo@ufpr.br" class="auth_mail" title="E-mail the corresponding author
- 关键词：Ruthenium nitrosyl ; Phosphorus&ndash ; nitrogen ligand ; Triarylphosphines ; 31P NMR ; Electrochemistry ; ESI-MS
- 刊名：Inorganica Chimica Acta
- 出版年：2017
- 出版时间：1 January 2017
- 年：2017
- 卷：454
- 期：Complete
- 页码：40-45
- 全文大小：916 K
文摘
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Four complexes with general formula [RuCl2(NO)(P–N)(PR3)]PF6 were synthesized.
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Effect of the PR3 on the properties of the complexes was evaluated.
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NO+ affects the Ru–P bond lengths, 31P NMR chemical shifts and 2Jpp.
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Inverse correlation of Ru–P versus δ31P (ppm) was found and extends the literature data.