Catalytic homogeneous oxidation of monoterpenes and cyclooctene with hydrogen peroxide in the presence of sandwich-type tungstophosphates [M₄(H₂O)₂(PW₉O₃₄)₂]ⁿ⁻, M = Co^II, Mn^II and Fe^III

详细信息    查看全文

• 作者：Isabel C.M.S. Santos^a ; ^{ivieira@ua.pt} ; José ; A.F. Gamelas^b ; Tiago A.G. Duarte^a ; Má ; rio M.Q. Simõ ; es^a ; ^{msimoes@ua.pt} ; ^{mario.quialheiro@gmail.com} ; M. Graç ; a P.M.S. Neves^a ; José ; A.S. Cavaleiro^a ; Ana M.V. Cavaleiro^c
• 关键词：Sandwich-type polyoxometalates ; Monoterpenes ; Cyclooctene ; Oxidation
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：593-599
• 全文大小：946 K
• 卷排序：426

文摘

Sandwich-type B‐α‐[M4(H2O)2(PW9O34)2]n− (M = CoII, MnII, FeIII) polyoxometalates. Oxidation of limonene, geraniol, linalool, carveol, and cyclooctene. Oxidation with 30% (w/w) aqueous hydrogen peroxide, in acetonitrile. The main/unique oxidation pathway for terpenoids and cyclooctene is epoxidation.