A graph G is uniquely k-colorable if the chromatic number of G is 4c03" title="Click to view the MathML source">k and G has only one 4c03" title="Click to view the MathML source">k-coloring up to permutation of the colors. A uniquely 4c03" title="Click to view the MathML source">k-colorable graph G is edge-critical if G−e is not a uniquely 4c03" title="Click to view the MathML source">k-colorable graph for any edge c05e0e2cbff9a12d9c8a0301cf1415b8" title="Click to view the MathML source">e∈E(G). Mel’nikov and Steinberg (Mel’nikov and Steinberg, 1977) asked to find an exact upper bound for the number of edges in an edge-critical uniquely 3-colorable planar graph with n vertices. In this paper, we give some properties of edge-critical uniquely 3-colorable planar graphs and prove that if G is such a graph with 749ca130999bee0778fe" title="Click to view the MathML source">n(≥6) vertices, then , which improves the upper bound 7430d79ef30ef705ca495b"> given by Matsumoto (Matsumoto, 2013). Furthermore, we find some edge-critical uniquely 3-colorable planar graphs with n(=10,12,14) vertices and edges.