The chromatic capacityχcap(G) of a graph G is the largest k for which there exists a k-coloring of the edges of G such that, for every coloring of the vertices of G with the same colors, some edge is colored the same as both its vertices. We prove that there is an unbounded function such that χcap(G)f(χ(G)) for almost every graph G, where χ denotes the chromatic number. We show that for any positive integers n and k with kn/2 there exists a graph G with χ(G)=n and 0b36abefbaf5915eb5f3bb778c74f8d6"" title=""Click to view the MathML source"" alt=""Click to view the MathML source"">χcap(G)=n-k, extending a result of Greene. We obtain bounds on 90b05c31def0a96e8a1dfbf118619c""> that are tight as r→∞, where is the complete n-partite graph with r vertices in each part. Finally, for any positive integers p and q we construct a graph G with χcap(G)+1=χ(G)=p that contains no odd cycles of length less than q.