Iridium-catalysed desilylative acylation of 1-alkenylsilanes

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• 作者：Maciej Zaranek^a ; Maciej Skrodzki^a ; Justyna Szudkowska-Frątczak^a ; Maciej Dodot^a ; Ireneusz Kownacki^a ; ^b ; Bartosz Orwat^a ; Piotr Pawluć^a ; ^b ; ^{piotrpaw@amu.edu.pl}
• 关键词：Iridium catalyst ; Desilylative acylation ; Anhydride ; Enone
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PA
• 页码：75-78
• 全文大小：461 K
• 卷排序：426

文摘

The iridium-catalysed desilylative acylation of vinylsilanes with acid anhydrides. Synthesis of (E)-styryl and (E,E)-buta-1,3-dien-1-yl ketones. Mechanism proposal of the [{Ir(μ-Cl)(cod)}2]-catalysed acylation of vinylsilanes.