Zeolite catalyzed highly selective synthesis of 2-methoxy-6-acetylnaphthalene by Friedel-Crafts acylation of 2-methoxynaphthalene in acetic acid reaction media

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• 作者：Tomoyoshi Yamazaki ; Makoto Makihara ; Kenichi Komura ; ^{kkomura@gifu-u.ac.jp}
• 关键词：Friedel-Crafts acetylation ; Zeolite ; Acetic acid ; 2-Methoxynaphthalene ; Shape-selectivity
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PA
• 页码：170-176
• 全文大小：883 K
• 卷排序：426

文摘

Highly selective synthesis of 2-methoxy-6-acetylnaphthalene from 2-methoxynaphthalene was achieved by using proton-type mordenite. High silica zeolites with 12-membered ring pore showed a high activity for this acylation reaction. Detailed control experiments were carried out to propose a plausible reaction mechanism.