Reactivity of organoplatinum complexes containing appended alcohol functional groups: Activation of dioxygen and hydrogen peroxide
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- 作者：Kyle A. Thompson ; Connor Kadwell ; Paul D. Boyle ; Richard J. Puddephatt ; pudd@uwo.ca
- 关键词：Platinum ; Oxidative addition ; Dioxygen ; Hydrogen peroxide
- 刊名：Journal of Organometallic Chemistry
- 出版年：2017
- 出版时间：1 February 2017
- 年：2017
- 卷：829
- 期：Complete
- 页码：22-30
- 全文大小：1590 K
- 卷排序：829
文摘
The reactivity of platinum(II) complexes [PtMe2(RN=CH-2-C5H4N)], R = CH2CH2OH or CH2CH2CH2OH, has been studied. Alkyl halides give trans oxidative addition. Dioxygen in methanol solution gives [Pt(OH)(OMe)Me2(RN=CH-2-C5H4N)]. When R = CH2CH2OH, reaction with oxygen also occurs in acetone solution. Cyclization of the imine ligand can occur.