Phosphorous bonding in PCl₃:H₂O adducts: A matrix isolation infrared and ab initio computational studies

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• 作者：Prasad Ramesh Joshi ; N. Ramanathan ; K. Sundararajan ; K. Sankaran ; ^{ksran@igcar.gov.in}
• 关键词：Phosphorus bonding ; Ab initio ; Matrix isolation ; AIM analysis ; NBO analysis
• 刊名：Journal of Molecular Spectroscopy
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：331
• 期：Complete
• 页码：44-52
• 全文大小：1022 K
• 卷排序：331

文摘

Non-covalent interaction between PCl3 and H2O studied using matrix isolation infrared spectroscopy. Experimental evidence obtained for phosphorus bonding in the adducts. AIM and NBO analyses accomplished to unravel the nature of interaction in the adducts.