Solution studies of some new oxamides – Co-ordination behaviour towards Cu(II) ions

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• 作者：Agnieszka Dobosz ; Jan Spycha&#x142 ; a ; Henryk Koz&#x142 ; owski ; Magdalena Rowi&#x144 ; ska ; Andrzej Temeriusz ; Holm Frauendorf ; Franc Meyer
• 关键词：Oxamides ; Copper(II) ; Copper(III) ; Electrochemistry ; Spectroscopy
• 刊名：Journal of Inorganic Biochemistry
• 出版年：2007
• 出版时间：October 2007
• 年：2007
• 卷：101
• 期：10
• 页码：1505-1516
• 全文大小：579 K

文摘

The co-ordination chemistry of some new oxamides towards Cu(II) ions was studied using various techniques: potentiometry, voltammetry, spectroscopy (UV–Vis, CD and EPR) and ESI–MS spectrometry. All tested compounds chelate the copper(II) ions with formation of 1:1 and 1:2 (metal-to-ligand ratio) complexes. The Cu(II) ions are bound by 1N, 2N or 3N nitrogen donor systems. Additionally, an unusual co-ordination to amide N-atoms without additional anchoring site is suggested. The ¹⁴N hyperfine splitting observed for the system ox6–Cu(II) above pH 10 clearly indicates the involvement of at least three N donor atoms in the copper ion binding. Moreover, the surrounding by three amide-N and one carbonyl-O stabilizes the high oxidation state of copper(III), although such complexes are very unstable in solution.