Thermal decomposition of AIBN Part C: SADT calculation of AIBN based on DSC experiments
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- 作者：Elena Moukhina ; elena.moukhina@netzsch.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：AIBN ; Azobisisobutyronitrile ; Kinetic modelling ; Thermal decomposition ; SADT ; DSC ; H.1 ; H.4
- 刊名：Thermochimica Acta
- 出版年：2015
- 出版时间：10 December 2015
- 年：2015
- 卷：621
- 期：Complete
- 页码：25-35
- 全文大小：3474 K
文摘
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The kinetic model for AIBN decomposition contains both exothermal (decomposition) and endothermal (melting) kinetic processes.
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It contains decomposition from both the solid and the liquid phases.
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Induction time for the 5, 20 and 50 kg packages for SADT temperatures is longer that SADT storage time.
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Safe temperatures have been found for the same packages for 60 days, exceeding the induction period.