Synthesis of a new conformationally constrained glycoamino acid building block
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- 作者：Avenoza ; Alberto ; Peregrina ; Jesú ; s M. ; San Martí ; n ; Emilio
- 关键词：amino acids and derivatives ; azides ; glycosidation ; peptide analogues/mimetics
- 刊名：Tetrahedron Letters
- 出版年：2003
- 出版时间：August 18, 2003
- 年：2003
- 卷：44
- 期：34
- 页码：6413-6416
- 全文大小：96.0 K
文摘
The synthesis of a suitably protected β-d-glucopyranosyl-(S)-α-methylserine derivative—a new conformationally constrained glycosylated quaternary amino acid analogue of β-d-glucopyranosyl-l-serine—is described. This compound can be used as an attractive building block for the synthesis of new, constrained glycopeptides.