Catalytic oxidation of primary aromatic alcohols using half sandwich Ir(III), Rh(III) and Ru(II) complexes: A practical and theoretical study
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- 作者：Saravanan Thangavela ; Subramaniam Boopathib ; N. Mahadevaiaha ; Ponmalai Kolandaivelb ; Pramod B. Pansuriyaa ; Holger B. Friedricha ; friedric@ukzn.ac.za" class="auth_mail" title="E-mail the corresponding author ; holgerbfriedrich@gmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Catalytic oxidation ; N ; N&prime ; Bidentate ligand ; Half sandwich metal complexes ; Primary alcohols ; DFT
- 刊名：Journal of Molecular Catalysis A: Chemical
- 出版年：2016
- 出版时间：November 2016
- 年：2016
- 卷：423
- 期：Complete
- 页码：160-171
- 全文大小：2851 K
文摘
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Ir(III), Rh(III) and Ru(II) complexes show pseudo octahedral “piano-tool” geometry.
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Catalytic activity for benzyl alcohol oxidation demonstrated by all three complexes.
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Ir and Ru complexes show best conversion of primary aromatic alcohols to aldehydes.
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DFT studies carried out on the complexes.
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Proposed reaction mechanism is supported by DFT.