Inorganic–organic hybrid materials with zirconium oxoclusters as protective coatings on aluminium alloys

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• 作者：Fabrizio Girardi ; Francesco Graziola ; Paolo Aldighieri ; Lorenzo Fedrizzi ; Silvia Gross ; Rosa Di Maggio
• 关键词：Anticorrosion properties ; Hybrid inorganic– ; organic materials ; Oxocluster
• 刊名：Progress in Organic Coatings
• 出版年：2008
• 出版时间：June 2008
• 年：2008
• 卷：62
• 期：4
• 页码：376-381
• 全文大小：846 K

文摘

Inorganic–organic hybrid materials are attracting a strong scientific interest mainly for their outstanding inherent mechanical and thermal properties, which can be traced back to the intimate coupling of both inorganic and organic components. By carefully choosing the experimental parameters used for their synthesis, chemically and thermally stable acrylate-based hybrid material embedding the zirconium oxocluster Zr₄O₄(OMc)₁₂, where OMcCH₂C(CH₃)C(O)O, can be deposited as UV-cured films on aluminium alloys.