First iridium-catalyzed hydroformylation in a continuously operated miniplant
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- 作者：Alexander Kä ; mpera ; Sirisap Jenny Warrelmanna ; Kristina Reiswicha ; René ; Kuhlmanna ; Robert Frankeb ; c ; Arno Behra ; arno.behr@bci.tu-dortmund.de" class="auth_mail" title="E-mail the corresponding author
- 关键词：Homogeneous catalysis ; Hydroformylation ; Iridium catalyst ; Miniplant ; Continuous operation
- 刊名：Chemical Engineering Science
- 出版年：2016
- 出版时间：22 April 2016
- 年：2016
- 卷：144
- 期：Complete
- 页码：364-371
- 全文大小：1129 K
文摘
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Design, construction and start-up of a versatile miniplant.
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Successful scale-up of iridium-catalyzed hydroformylation for continuous operation.
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Long-term experiments up to 100 h showed high long-term catalyst stability and activity.
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Various substrates such as 1-octene and 1-pentene applied.
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Highly efficient catalyst recycling via extraction with catalyst leaching of 0.1%/h.