(CAAC)CuX-catalyzed hydroboration of terminal alkynes with pinacolborane directed by the X-ligand

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• 作者：Erik A. Romero ; Rodolphe Jazzar ; Guy Bertrand ; ^{guybertrand@ucsd.edu}
• 关键词：Hydroboration ; Homogenous catalysis ; Copper ; Carbene ; Terminal alkynes
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：829
• 期：Complete
• 页码：11-13
• 全文大小：402 K
• 卷排序：829

文摘

Selective (E)-β-hydroboration of terminal alkynes with pinacol borane. Simple and efficient synthetic protocol with low catalyst loading and facile isolation. Commercially available ligands and cheap abundant metal.