Hydrogenation of methyl isobutyl ketone over bifunctional Pt-zeolite catalyst

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• 作者：Mshari A. Alotaibi ; Elena F. Kozhevnikova ; Ivan V. Kozhevnikov
• 关键词：Methyl isobutyl ketone ; Hydrogenation ; Platinum ; Zeolite ; Bifunctional catalysis
• 刊名：Journal of Catalysis
• 出版年：2012
• 出版时间：September, 2012
• 年：2012
• 卷：293
• 期：Complete
• 页码：141-144
• 全文大小：375 K

文摘

Methyl isobutyl ketone (MIBK) can be viewed as a key intermediate for the conversion of biomass-derived acetone - the by-product of biobutanol production - to transportation fuel. Zeolite H-ZSM-5 doped with Pt nanoparticles was found to be a highly efficient catalyst for gas-phase hydrogenation of MIBK to methylpentanes with >99 % yield at 200 ¡ãC. The reaction proceeds via bifunctional metal-acid catalysed pathway involving MIBK hydrogenation to 4-methyl-2-pentanol (MP-ol) on metal sites followed by MP-ol dehydration on acid sites to form olefin and finally olefin hydrogenation to 2-methylpentane (2MP) on metal sites, with all three steps occurring on a single catalyst bed. 2MP thus obtained underwent isomerisation over bifunctional Pt/H-ZSM-5 catalyst to give a mixture of 2- and 3-methylpentanes in a ratio of 83:17. The catalyst did not show any deactivation for at least 16 h on stream.