Mild homogeneous oxidation and hydrocarboxylation of cycloalkanes catalyzed by novel dicopper(II) aminoalcohol-driven cores

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• 作者：Tiago A. Fernandes ; Vâ ; nia André ; Alexander M. Kirillov ; ^{kirillov@tecnico.ulisboa.pt} ; Marina V. Kirillova ; ^{kirillova@tecnico.ulisboa.pt}
• 关键词：C&ndash ; H functionalization ; Oxidation ; Hydrocarboxylation ; Cycloalkanes ; Homogeneous catalysis ; Copper compounds
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2017
• 出版时间：January 2017
• 年：2017
• 卷：426
• 期：part_PB
• 页码：357-367
• 全文大小：2743 K
• 卷排序：426

文摘

Two new dicopper(II) coordination compounds were synthesized and fully characterized. These compounds catalyze the mild homogeneous oxidation of alkanes. Effects of different reaction parameters were evaluated. Unusual promoting a role of water was detected and investigated. The compounds also catalyze the hydrocarboxylation of alkanes to carboxylic acids.