In situ generated Pd(0) nanoparticles stabilized by bis(aryl)acenaphthenequinone diimines as catalysts for aminocarbonylation reactions in water

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• 作者：P. Wó ; jcik^a ; V. Rosar^b ; A. Gniewek^a ; B. Milani^b ; ^{milaniba@units.it} ; A.M. Trzeciak^a ; ^{anna.trzeciak@chem.uni.wroc.pl}
• 关键词：Palladium ; α-diimines ; Aminocarbonylation ; Aqueous medium ; α-ketoamides
• 刊名：Journal of Molecular Catalysis A: Chemical
• 出版年：2016
• 出版时间：15 December 2016
• 年：2016
• 卷：425
• 期：Complete
• 页码：322-331
• 全文大小：2206 K
• 卷排序：425

文摘

High catalytic activity in aminocarbonylation of the in situ formed Pd-nanoparticles. Excellent recycling of Pd-nanoparticles stabilized with diimine ligands only. Phosphine-free aminocarbonylation in water at ambient CO pressure. Efficient formation of α-ketoamides at 10 atm of CO performed without any additives.