Experimental and computational study of the thermodynamic properties of 2-nitrofluorene and 2-aminofluorene
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- 作者：Juliana A.S.A. Oliveiraa ; Manuel J.S. Montea ; mjmonte@fc.up.pt" class="auth_mail ; R. Notariob ; Maria D.M.C. Ribeiro da Silvaa
- 关键词：2-Aminofluorene ; 2-Nitrofluorene ; Enthalpy ; Entropy ; Gibbs energy ; Calorimetry ; Combustion ; Sublimation ; Fusion ; Vapour pressure ; Computational thermochemistry ; G3 and G4 calculations
- 刊名：Journal of Chemical Thermodynamics
- 出版年：September 2014
- 年：2014
- 卷：76
- 期：Complete
- 页码：56-63
- 全文大小：794 K
文摘
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A thermodynamic study of two fluorene derivatives is presented.
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Vapour pressures and energies of combustion were measured.
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Enthalpy, entropy and Gibbs energy of sublimation were derived.
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Enthalpy and Gibbs energy of formation in crystal and gas phases were calculated.
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Gas phase enthalpy of formation was also estimated by quantum chemical calculations.