Triple ionisation of methane by double Auger and related pathways

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• 作者：J.H.D. El ; P. Linusson ; L. Hedin ; E. Andersson ; J.-E. Rubensson ; R. Feifel
• 刊名：Chemical Physics Letters
• 出版年：2010
• 出版时间：18 January 2010
• 年：2010
• 卷：485
• 期：1-3
• 页码：21-25
• 全文大小：334 K

文摘

Triple ionisation of methane by decay of the singly charged ion with a 1s vacancy produces a trication spectrum starting near 70 eV binding energy. Vibrational excitation in the initial hole state broadens and shifts the triple ionisation bands. Ionisation through core-valence doubly ionised states gives lower triple ionisation onsets and changes the spectral intensity pattern in accordance with retention of the initial valence holes in course of the double Auger effect. The double Auger effects occur both directly and as cascades, the different pathways producing different electron distributions and final state spectra.