NH3, NOx, HTC-RN, NO3−, and NH4+ were measured in fresh smoke from two wildfires.
Enhanced concentrations of all reactive nitrogen species except NH4+ were observed.
Ammonia during smoke-impacted periods was enhanced by a factor of 20.
Excess mixing ratios NH3 relative to excess CO were found to be 0.027 ± 0.002.
Excess mixing ratios NOx relative to excess CO were found to be 0.057 ± 0007.