Voltammetry at a single nano-electrode by varying electrode diameters: Review
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- 作者：Koichi Jeremiah Aoki kaoki@u-fukui.ac.jp" class="auth_mail" title="E-mail the corresponding author
- 关键词：Nano-electrodes ; Heterogeneous rate constants ; Memory effects of diffusion ; Formation of multi-valent ions without supporting electrolyte
- 刊名：Journal of Electroanalytical Chemistry
- 出版年：2016
- 出版时间：15 October 2016
- 年：2016
- 卷：779
- 期：Complete
- 页码：7-17
- 全文大小：1092 K
文摘
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Heterogeneous rate constants by steady-state currents are too large to be evaluated.
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Di-anions of the redox species are not generated without salt.
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Saito's equation is valid for diameters larger than 4 μm, owing to the memory effects.