Total synthesis of (¡À)-monomorine

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• 作者：Tri Q. Le ; Robert M. Oliver III ; Joel T. Arcari ; Mark J. Mitton-Fry
• 关键词：Hydrogenation ; Claisen-Schmidt ; Monomorine
• 刊名：Tetrahedron Letters
• 出版年：2012
• 出版时间：17 October, 2012
• 年：2012
• 卷：53
• 期：42
• 页码：5660-5662
• 全文大小：355 K

文摘

An efficient, two-operation synthesis of the trail ant pheromone (¡À)-monomorine is reported. The synthesis features an aqueous Claisen-Schmidt condensation followed by the stereocontrolled installation of the three resident stereocenters in a single operation.