A two-dimensional metal-organic framework composed of paddle-wheel cobalt clusters with permanent porosity

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• 作者：Stephen Charles King ; Hailong Wang ; ^{hailong.wang@utsa.edu} ; Hadi D. Arman ; Banglin Chen ; ^{banglin.chen@utsa.edu}
• 刊名：Inorganic Chemistry Communications
• 出版年：2016
• 出版时间：December 2016
• 年：2016
• 卷：74
• 期：Complete
• 页码：98-101
• 全文大小：742 K
• 卷排序：74

文摘

A cobalt(II)-organic framework, [Co2(TPEC)(DMA)2]·(DMA)3 (1) (H2TPEC = 1,1,2,2-tetra(4-(4-carboxyl-phenyl)benzenyl)ethene; DMA = N,N′’-dimethylacetamide), was synthesized and characterized by single crystal diffraction analysis. The structure shows a two-dimensional (2D) sheet composed of paddle-wheel Co2(COO)4 clusters linking TPEC ligands. The permanent porosity was established for the activated phase and gas sorption isotherms acquired.