A hydroperoxo-rebound mechanism of alkane oxidation with hydrogen peroxide catalyzed by binuclear manganese(IV) complex in the presence of an acid with involvement of atmospheric dioxygen

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• 作者：Georgiy B. Shul&rsquo ; pin^a ; ^b ; ^{Shulpin@chph.ras.ru} ; ^gbsh@mail.ru ; Dmytro S. Nesterov^c ; Lidia S. Shul&rsquo ; pina^d ; Armando J.L. Pombeiro^c
• 关键词：Alkanes ; Oxygenation ; Rebound mechanism ; Hydroperoxides ; Triphenylphosphine ; Labeled dioxygen
• 刊名：Inorganica Chimica Acta
• 出版年：2017
• 出版时间：30 January 2017
• 年：2017
• 卷：455
• 期：part_P2
• 页码：666-676
• 全文大小：1250 K
• 卷排序：455

文摘

A new mechanism is proposed for the alkane oxidation with H2O2. This very efficient oxidation is catalyzed by a binuclear Mn(IV) complex. In the absence of a small amount of added carboxylic acid the reaction does not occur. Reaction proceeds stereoselectively. Alkyl hydroperoxides are the main primary products.