Selective CH functionalization of electron-deficient aromatics by carbamoylsilanes: synthesis of aromatic carbinolamines or amides
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- 作者：Yanhong Liu ; Pei Cao ; Jianxin Chen ; jjxxcc2002@yahoo.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Carbamoylsilanes ; Carbinolamines ; Amides ; CH functionalization ; Synthetic methods
- 刊名：Tetrahedron Letters
- 出版年：2016
- 出版时间：24 February 2016
- 年：2016
- 卷：57
- 期：8
- 页码：937-941
- 全文大小：2594 K
文摘
Selective C
H functionalization of electron-deficient aromatics with various carbamoylsilanes is developed under catalysts-free conditions. These transformations provide a facile and efficient method for synthesizing some tertiary or secondary aromatic carbinolamines and amides in good yields.
H functionalization of electron-deficient aromatics with various carbamoylsilanes is developed under catalysts-free conditions. These transformations provide a facile and efficient method for synthesizing some tertiary or secondary aromatic carbinolamines and amides in good yields.