where aH+ is the proton activity.
The influence of ΔG on fluorite dissolution rate at pH 2 was investigated by means of AFM and VSI surface measurements and flow-through experiments with powdered fluorite. The fluorite dissolution rate decreases non-linearly with increasing Gibbs energy (ΔG) and a dissolution plateau is obtained at ΔG −7 kcal mol−1. This ΔG effect can be expressed with a rate law of the form An alternative form based on a formulation making use of a Temkin number is also possible Dissolution proceeds by formation of equilateral triangular etch pits with trigonal pyramidal morphology and emanation of stepwaves that are responsible for the surface retreat. The results of Monte Carlo simulations are consistent with this reaction mechanism.