Diels-Alder reactions of arynes in situ generated from DA reaction between bis-1,3-diynes and alkynes

详细信息    查看全文

• 作者：Ming-Xing Zhang^&dagger ; ; Wei Shan^&dagger ; ; Zhao Chen ; Jun Yin ; Guang-Ao Yu ; ^{yuguang@mail.ccnu.edu.cn" class="auth_mail" title="E-mail the corresponding author} ; Sheng Hua Liu ; ^{chshliu@mail.ccnu.edu.cn" class="auth_mail" title="E-mail the corresponding author}
• 关键词：Diels&minus ; Alder reactions ; Arynes ; Bis-1 ; 3-diynes ; Ring compounds
• 刊名：Tetrahedron Letters
• 出版年：2015
• 出版时间：9 December 2015
• 年：2015
• 卷：56
• 期：49
• 页码：6833-6838
• 全文大小：3518 K

文摘

Diels–Alder reactions based on arynes generated directly from bis-1,3-diynes have been developed. These reactions displayed good functional group compatibility and gave moderate to high yields under mild conditions. Such synthetic methodology can be effectively used for the synthesis of complicated ring compounds.