Difference in α-thiocyanation of malonates, β-oxo esters and β-diketones with sodium thiocyanate and cerium(IV) ammonium nitrate

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• 作者：Alexander O. Terent&rsquo ; ev^a ; ^b ; ^{terentev@ioc.ac.ru" class="auth_mail" title="E-mail the corresponding author} ; Mikhail Yu. Sharipov^a ; ^b ; Alexey P. Glinuskin^c ; Igor B. Krylov^a ; Darya V. Gaidarenko^b ; Gennady I. Nikishin^a
• 刊名：Mendeleev Communications
• 出版年：2016
• 出版时间：May-June 2016
• 年：2016
• 卷：26
• 期：3
• 页码：226-227
• 全文大小：146 K

文摘

β-Diketones and β-oxo esters are thiocyanated with the NaSCN/(NH₄)₂ Ce(NO₃)₆ system or with pre-generated dirhodanogen. Malonates undergo thiocyanation only with the NaSCN/(NH₄)₂ Ce(NO₃)₆ system.