Synthesis and characterization of two novel organocation containing group 13 metal ethylenediphosphonates
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- 作者：Attfield ; Martin P. ; Harvey ; Howard G. ; Teat ; Simon J.
- 关键词：Aluminum ; Gallium ; Diphosphonate ; Hybrid organic&ndash ; inorganic material ; Crystal structure ; Edge-sharing octahedra
- 刊名：Journal of Solid State Chemistry
- 出版年：2004
- 出版时间：August, 2004
- 年：2004
- 卷：177
- 期：8
- 页码：2951-2960
- 全文大小：525 K
文摘
Two novel group 13 metal diphosphonates: (H3NC3H6NH3)2[Al2F6(O3PC2H4PO3)]·H2O (1) (monoclinic, C2/c, a=16.9697(7)Å, b=8.0273(4)Å, c=16.3797(8)Å, β=117.762(2)°, Z=4, R1