Solution and structural binding studies of phosphate with thiophene-based azamacrocycles
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- 作者：Syed A. Haquea ; Rainier S. Berkleya ; Frank R. Fronczekb ; Md. Alamgir Hossaina ; alamgir.hossain@jsums.edu" class="auth_mail" title="E-mail the corresponding author
- 关键词：Azamacrocycle ; Ditopic complex ; Anion binding ; Phosphate complex
- 刊名：Inorganic Chemistry Communications
- 出版年：2016
- 出版时间：August 2016
- 年：2016
- 卷：70
- 期：Complete
- 页码：121-124
- 全文大小：614 K
文摘
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Ditopic binding of phosphate to thiophene-based azmamcrocycles is reported.
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The formation of phosphate complex is supported by proton and phosphorous NMR.
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Phosphate complex is stabilized multiple hydrogen bonds from NH ⋯ O and CH ⋯ O interactions.