Hydrodynamics and mass transfer in three-phase composite minichannel fixed-bed reactors

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• 作者：S. Haase ; M. Weiss ; R. Langsch ; T. Bauer ; R. Lange ; ^{ruediger.lange@tu-dresden.de}
• 关键词：Hydrodynamics ; Mass transfer ; Minichannel ; Multiphase reactors ; Packed bed ; Pellet-string
• 刊名：Chemical Engineering Science
• 出版年：2013
• 出版时间：3 May, 2013
• 年：2013
• 卷：94
• 期：Complete
• 页码：224-236
• 全文大小：1078 K

文摘

The improved mass transfer and reduced macroscopic backmixing of segmented flow regimes in mini and microchannels favour its application in three-phase reaction processes. Therefore, industrial available and standardised catalyst particles or pellets may benefit from these microfluidic phenomena if they are packed into inert minichannels. Such packings form the key components of composite minichannel reactors. In order to evaluate this reactor concept, hydrodynamic phenomena, mass transfer, and pressure drop will be examined for a reactor consisting of a ceramic minichannel packing with a hydraulic diameter of 1.0 mm and dumped spherical catalyst particles of 0.8 mm in diameter. The experimental data, achieved in a setup combining hydrodynamic observation and chemical reaction, were used to derive universal applicable correlations to predict mass transfer coefficients and friction factors from Reynolds, Schmidt, and Sherwood numbers. The work concludes with an extensive comparison of composite minichannel reactors with conventional multiphase reactors and developing packed-bed reactors in terms of mass transfer capability, power consumption, and contacting efficiency.

At identical power consumption, the investigated composite minichannel reactor offered a remarkably higher overall mass transfer rate for the gaseous compound than conventional trickle-bed, slurry bubble column, or slurry stirred tank reactors. Similar rates or even higher rates were achieved in miniaturised packed-bed reactors with particles less than 1.0 mm in diameter. Consequently, it is expected that structured and miniaturised packed-bed reactors are a promising concept to intensify multiphase reaction processes, e.g. by switching from batch to continuous processing.