A study of the glass formation and crystallization in the mixed fluorozirconate-phosphate systems ZrF4-BaF2(SnF2)-NaPO3
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- 作者：Vladimir K. Goncharuka ; gon@ich.dvo.ru" class="auth_mail" title="E-mail the corresponding author ; Irina G. Maslennikovaa ; masl@ich.dvo.ru" class="auth_mail" title="E-mail the corresponding author ; Valerii I. Kharchenkoa ; b ; vikharchenko@gmail.com" class="auth_mail" title="E-mail the corresponding author ; vikharchenko@ich.dvo.ru" class="auth_mail" title="E-mail the corresponding author ; Valeriy Ya. Kavuna ; kavun@ich.dvo.ru" class="auth_mail" title="E-mail the corresponding author ; Arseniy B. Slobodyuka ; ampy@ich.dvo.ru" class="auth_mail" title="E-mail the corresponding author ; Sergey A. Sarina ; zveroboy82@gmail.com" class="auth_mail" title="E-mail the corresponding author
- 关键词：Fluorozirconate&ndash ; phosphate glass ; Glass network ; Globules ; MAS NMR ; DTA ; SAXS ; TEM
- 刊名：Journal of Non-Crystalline Solids
- 出版年：2016
- 出版时间：1 January 2016
- 年：2016
- 卷：431
- 期：Complete
- 页码：118-125
- 全文大小：978 K
文摘
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ZrF4–BaF2(SnF2)–NaPO3, 53ZrF4-30BaF2–(17 − x)NaPO3–xMF3 glasses (1 ≤ x ≤ 5) were studied.
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Behavior and properties of these glasses are similar to fluorozirconate glasses.
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The fluorozirconate and phosphate subsystems in the glasses coexist independently.
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The glass microstructure is globular with a particle diameter of 50–560 Å.
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These glasses can be used as precursors for the mixed optical nanoceramics.