Studies on kinetics and mechanism of thermal decomposition of yttrium tartrate trihydrate crystals

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• 作者：K.K. Bamzai ; Sanjay Kumar
• 关键词：Differential thermal analysis (DTA) ; Thermogravimetric analysis (TGA) ; Thermal properties ; Organometallic compounds
• 刊名：Materials Chemistry and Physics
• 出版年：2008
• 出版时间：15 February 2008
• 年：2008
• 卷：107
• 期：2-3
• 页码：200-207
• 全文大小：337 K

文摘

Thermogravimetric and differential thermal studies have been used for kinetics and mechanism of thermal decomposition of gel grown crystals of yttrium tartrate trihydrate. Studies have been carried under non-isothermal conditions ranging from 25 to 1000 °C. The material is stable up to 218 °C and becomes anhydrous at 275 °C. The decomposition process occurs in four stages until a complex of yttrium oxide-carbonate is formed at 700 °C. The energies of the reactions involved and the mechanism of decomposition at each stage have been examined. The values of kinetic parameters, viz., order of reaction, activation energy and the frequency factor have been evaluated by using the relations Horowitz–Metzger, Coats–Redfern and Piloyan–Novikova. The proposed model for thermal decomposition of the material for all the stages of decomposition is random nucleation model and the order of reaction is one. The final product, that is, yttrium oxide-carbonate has been confirmed by energy dispersive X-ray (EDAX) studies carried on the sample-heated up to 1000 °C for thermal analysis.