Synthesis and characterization of the heavy alkaline earth aryloxide congeners
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- 作者：Timothy J. Boyle ; tjboyle@Sandia.gov ; Leigh Anna M. Steele ; Alia Saad
- 关键词：Alkaline earth alkoxides ; Barium ; Strontium ; Aryloxides
- 刊名：Inorganica Chimica Acta
- 出版年：2013
- 出版时间：1 January, 2013
- 年：2013
- 卷：394
- 期：Complete
- 页码：259-268
- 全文大小：1244 K
文摘
A series of the heavier alkaline earth (AE) aryloxides were synthesized from the reaction of the metal (AE¡ã) or the ¡®AE(ONep)2¡¯ (ONep = neo-pentoxide) precursor with a series of 2,6-di-alkyl phenols (alkyl = methyl (H-DMP), iso-propyl (H-DIP), tert-butyl (H-DBP)). These products were crystallographically characterized as: [(py)3(DMP)Sr(¦Ì-DMP)]2¡¤py (1), [Sr(DIP)2(py)4] (2), [Sr(DBP)2(py)3] (3), [(py)3Ba(¦Ì-DMP)3Ba(DMP)(py)2][Ba[(¦Ì-DMP)3Ba(py)3]2] (4), and [Ba(OAr)2(py)n] where OAr = DIP, n = 4 (5), DBP, n = 3 (6). In some instances AE-oxide alkoxides were crystallographically identified and have been preliminarily identified by single crystal X-ray diffraction. NMR data showed a single set of resonances for 1-6, which argues for monomeric species to exist in solution.