Quantification of ³⁹Ar recoil ejection from GA1550 biotite during neutron irradiation as a function of grain dimensions

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• 作者：Jeffrey H. Paine ; Sé ; bastien Nomade and Paul R. Renne
• 刊名：Geochimica et Cosmochimica Acta
• 出版年：2006
• 出版时间：15 March 2006
• 年：2006
• 卷：70
• 期：6
• 页码：1507-1517
• 全文大小：409 K

文摘

This study presents the first measurement of ³⁹Ar recoil ejection loss from individual, dimensionally characterized mineral grains due to neutron irradiation, and reveals the extent to which this recoil loss is problematic for ⁴⁰Ar/³⁹Ar dating. Using the well-characterized biotite standard GA1550, known to have between grain reproducibility of ⁴⁰Ar*/³⁹Ar_K of order 0.1 % , we measured the thicknesses (3–210 μm) and surface areas (0.07–0.90 mm²) of 159 grains selected to span the dimensional range represented in the aliquot. Thinner grains with high surface area/volume (SA/V) reveal elevated ⁴⁰Ar/³⁹Ar, as much as 26 % higher than thicker grains expected to suffer proportionately negligible depletion. Although the thinner grains yield intrinsically less precise measurements due to small ³⁹Ar ion beams, a regular decrease in net recoil loss with increasing biotite grain thickness is clear for grains thinner than ca. 50 μm. Grains thicker than 50 μm reveal essentially no ³⁹Ar loss within analytical uncertainties. The measured ³⁹Ar loss spectrum is significantly higher than predicted by previous modeling approaches. These results suggest a practical threshold of ca. 50 μm grain thickness for biotites, and probably other phyllosilicates, irradiated with ²³⁵U fission spectrum neutrons in order to avoid recoil artifacts. Poor agreement between our data and simulation results indicates that recoil displacement models should be revisited in order to resolve the discrepancy. Further empirical work to determine the recoil loss of ³⁹Ar in other minerals is important not only for routine age measurements, but also to shed more light on the role of recoil in multi-diffusion domain theory and other thermochronologic applications exploiting variable diffusion radii and/or grain size effects.