文摘
The impact of additives (La, Al and Mg) at the SiO<sub>2sub>/high-¦Ê interface has been investigated through ab initio simulations and electrical measurements. Various gate stacks with additive below or the above high-¦Ê dielectric are compared. Combination of capacitance versus gate bias measurement and internal photon emission is performed to demonstrate that the threshold voltage shift is related to a dipole formation at the SiO<sub>2sub>/high-¦Ê interface. The respective roles of aluminum and lanthanum are clearly identified as well as their sensitivity to roll-off. Impact of additive on metal gate function is studied. Finally, ab initio enables an analysis of the dipole formation with additive at the SiO<sub>2sub>/HfO<sub>2sub> interface.