The structural configurations of Ethylene Trithiocarbonate in the binary mixture (SCS₂CH₂CH₂+CHCl₃) investigated by polarized Raman: Experimental and quantum chemical results

详细信息    查看全文

• 作者：Ran Zhou^a ; Fengqi Wu^a ; Xiaoshun Zhou^b ; Huigang Wang^a ; ^{huigwang@uni-osnabrueck.de} ; ^{zdwhg@163.com} ; Xuming Zheng^a ;
• 关键词：CS stretching ; Blue-shift ; Vibration coupling ; Ethylene Trithiocarbonate
• 刊名：Journal of Molecular Structure
• 出版年：2017
• 出版时间：5 February 2017
• 年：2017
• 卷：1129
• 期：Complete
• 页码：205-210
• 全文大小：862 K
• 卷排序：1129

文摘

The polarized Raman spectra & its absolute cross-section of ET in CHCl3 were analyzed. Aggregated model were firstly proposed to explain the NCE behaviors. Vibrational spectra & depolarization-ratio of ET and its dimer were calculated. Antiparallel CS vibrational coupling account for its frequency shift & NCE behavior.