刊名:Journal of Quantitative Spectroscopy and Radiative Transfer
出版年:2017
出版时间:January 2017
年:2017
卷:187
期:Complete
页码:124-134
全文大小:3991 K
卷排序:187
文摘
Equilibrium configuration of carbon dioxide molecule trapped in structure I clathrate hydrates is determined. Shifts of the vibrational frequencies of the CO2 molecule are calculated using contact transformation method. The orientational motions of the CO2 molecule are studied. The level schemes correspond to librational motions. The infrared absorption coefficients are calculated and correspond to pure vibrational transitions.