Mixed-metal cluster chemistry. 39. Syntheses and X-ray structures of Mo₃Ir₃(μ₄-η²-CO)(μ₃-CO)(CO)₁₀(η⁵-C₅H₅)₃ and Mo₃RhIr₃(μ-CO)₄(CO)₇(η⁵-C₅H₅)₃(η^5<

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• 作者：Junhong Fu ; Michael D. Randles ; Graeme J. Moxey ; Rob Stranger ; Marie P. Cifuentes ; Mark G. Humphrey ; ^{Mark.Humphrey@anu.edu.au}
• 关键词：Molybdenum ; Rhodium ; Iridium ; Carbonyl ; Cluster
• 刊名：Journal of Organometallic Chemistry
• 出版年：2017
• 出版时间：1 February 2017
• 年：2017
• 卷：829
• 期：Complete
• 页码：66-70
• 全文大小：888 K
• 卷排序：829

文摘

Edge-bridged trig. bipy. Mo3Ir3(μ4-η2-CO)(μ3-CO)(CO)10(η5-C5H5)3 (1) was obtained. Bicapped trig. bipy. Mo3RhIr3(μ-CO)4(CO)7(η5-C5H5)3(η5-C5Me5) (2) was obtained from 1. Differing electron counts of 2 and W3Ir4(μ-H)(CO)12(η5-C5H5)3 (3) were rationalized.