Construction of hydrogen-bonded networks of 1′,1‴-diboronic acids of biferrocene and biferrocenium cation
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- 作者：Keishiro Taharaa ; taharak@msnaist.jp" class="auth_mail" title="E-mail the corresponding author ; Tetsuhiro Akitaa ; Shiomi Yabumotoa ; Nazuna Terashitaa ; Shohei Kataoa ; Jun-ichi Kikuchia ; jkikuchi@ms.naist.jp" class="auth_mail" title="E-mail the corresponding author ; Ken Tokunagab
- 关键词：Biferrocene ; Biferrocenium ; Boronic acid ; Hydrogen-bonding
- 刊名：Journal of Organometallic Chemistry
- 出版年：2016
- 出版时间：1 March 2016
- 年：2016
- 卷：805
- 期：Complete
- 页码：139-147
- 全文大小：2334 K
文摘
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Supramolecular structures of biferrocene and biferrocenium is reported.
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Biferrocenediboronic acid formed hydrogen-bonded 1D chains in the solid state.
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Solvent molecules capped or connected the 1D chains by hydrogen-bonding.
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Biferroceniumdiboronic acid formed hydrogen-bonded 1D chains and discrete dimers.
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The valence states of biferrocenium were detrapped and trapped, respectively.